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Gaunt MJ, Sneddon HF, Hewitt PR, et al. Development of beta-keto 1,3-dithianes as versatile intermediates for organic synthesis. Org Biomol Chem. 2003;1(1):15-6doi: 10.1039/b208982c.
Gaunt, M. J., Sneddon, H. F., Hewitt, P. R., Orsini, P., Hook, D. F., & Ley, S. V. (2003). Development of beta-keto 1,3-dithianes as versatile intermediates for organic synthesis. Organic & biomolecular chemistry, 1(1), 15-6. https://doi.org/10.1039/b208982c
Gaunt, Matthew J, et al. "Development of beta-keto 1,3-dithianes as versatile intermediates for organic synthesis." Organic & biomolecular chemistry vol. 1,1 (2003): 15-6. doi: https://doi.org/10.1039/b208982c
Gaunt MJ, Sneddon HF, Hewitt PR, Orsini P, Hook DF, Ley SV. Development of beta-keto 1,3-dithianes as versatile intermediates for organic synthesis. Org Biomol Chem. 2003 Jan 07;1(1):15-6. doi: 10.1039/b208982c. PMID: 12929380.
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Org Biomol Chem. 2003 Jan 07;1(1):15-6. doi: 10.1039/b208982c.

Development of beta-keto 1,3-dithianes as versatile intermediates for organic synthesis.

Organic & biomolecular chemistry

Matthew J Gaunt, Helen F Sneddon, Peter R Hewitt, Paolo Orsini, David F Hook, Steven V Ley

Affiliations

  1. University Chemical Laboratory, Lensfield Road, Cambridge, UK CB2 1EW.

PMID: 12929380 DOI: 10.1039/b208982c

Abstract

beta-Keto 1,3-dithianes can be generated by the double conjugate addition of dithiols to propargylic ketones, esters and aldehydes in excellent yields. As masked 1,3-dicarbonyl systems these substrates can be converted to a range of functionalised oxygen-containing heterocycles that can be used in natural product synthesis.

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