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Chem Commun (Camb). 2003 Aug 21;(16):2082-3. doi: 10.1039/b305264h.

In situ UV-visible assessment of extent of reduction during oxidation reactions on oxide catalysts.

Chemical communications (Cambridge, England)

Morris D Argyle, Kaidong Chen, Carlo Resini, Catherine Krebs, Alexis T Bell, Enrique Iglesia

Affiliations

  1. Chemical Division, Lawrence Berkeley National Laboratory, Department of Chemical Engineering, University of California at Berkeley, Berkeley, CA 94720-1462, USA.

PMID: 12934922 DOI: 10.1039/b305264h

Abstract

The extent of reduction of active centers during oxidative alkane dehydrogenation on VOx/Al2O3 was measured from pre-edge UV-visible spectral features and found to increase with increasing VOx domain size and propane/O2 ratio.

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