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MacAdams LA, Buffone GP, Incarvito CD, et al. A stable alkyl hydride of a first row transition metal. Chem Commun (Camb). 2003;(10):1164-5doi: 10.1039/b301943h.
MacAdams, L. A., Buffone, G. P., Incarvito, C. D., Golen, J. A., Rheingold, A. L., & Theopold, K. H. (2003). A stable alkyl hydride of a first row transition metal. Chemical communications (Cambridge, England), (10), 1164-5. https://doi.org/10.1039/b301943h
MacAdams, Leonard A, et al. "A stable alkyl hydride of a first row transition metal." Chemical communications (Cambridge, England) vol. ,10 (2003): 1164-5. doi: https://doi.org/10.1039/b301943h
MacAdams LA, Buffone GP, Incarvito CD, Golen JA, Rheingold AL, Theopold KH. A stable alkyl hydride of a first row transition metal. Chem Commun (Camb). 2003 May 21;(10):1164-5. doi: 10.1039/b301943h. PMID: 12778716.
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Chem Commun (Camb). 2003 May 21;(10):1164-5. doi: 10.1039/b301943h.

A stable alkyl hydride of a first row transition metal.

Chemical communications (Cambridge, England)

Leonard A MacAdams, Gerald P Buffone, Christopher D Incarvito, James A Golen, Arnold L Rheingold, Klaus H Theopold

Affiliations

  1. Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA.

PMID: 12778716 DOI: 10.1039/b301943h

Abstract

Hydrogenolysis of a Cr(III) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane.

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