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Acta Crystallogr C. 2003 Dec;59:o694-5. doi: 10.1107/s0108270103024867. Epub 2003 Nov 14.

Betainohydroxamic acid chloride.

Acta crystallographica. Section C, Crystal structure communications

Dubravka Matković-Calogović, Erim Besić, Mladen Birus, Mario Gabricević

Affiliations

  1. Laboratory of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia.

PMID: 14671373 DOI: 10.1107/s0108270103024867

Abstract

The title compound, N-hydroxy-2-(trimethylammonio)acetamide chloride, C(5)H(13)N(2)O(2)(+).Cl(-), has been synthesized and structurally characterized. The structure consists of betainohydroxamic acid cations and Cl(-) anions linked by N-H.Cl and O-H.Cl hydrogen bonds into chains along [001]. It was found that the positive inductive effect of the charged N atom in close proximity to the hydroxamate carbonyl O atom has a negligible effect on the hydroxamic C-N bond length.

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