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Money VA, Radosavljevic Evans I, Elhaïk J, et al. An X-ray powder diffraction study of the spin-crossover transition and structure of bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate. Acta Crystallogr B. 2004;60:41-5doi: 10.1107/S0108768103027897.
Money, V. A., Radosavljevic Evans, I., Elhaïk, J., Halcrow, M. A., & Howard, J. A. (2004). An X-ray powder diffraction study of the spin-crossover transition and structure of bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate. Acta crystallographica. Section B, Structural science, 6041-5. https://doi.org/10.1107/S0108768103027897
Money, Victoria A, et al. "An X-ray powder diffraction study of the spin-crossover transition and structure of bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate." Acta crystallographica. Section B, Structural science vol. 60 (2004): 41-5. doi: https://doi.org/10.1107/S0108768103027897
Money VA, Radosavljevic Evans I, Elhaïk J, Halcrow MA, Howard JA. An X-ray powder diffraction study of the spin-crossover transition and structure of bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate. Acta Crystallogr B. 2004 Feb;60:41-5. doi: 10.1107/S0108768103027897. Epub 2004 Jan 21. PMID: 14734843.
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Acta Crystallogr B. 2004 Feb;60:41-5. doi: 10.1107/S0108768103027897. Epub 2004 Jan 21.

An X-ray powder diffraction study of the spin-crossover transition and structure of bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate.

Acta crystallographica. Section B, Structural science

Victoria A Money, Ivana Radosavljevic Evans, Jerome Elhaïk, Malcolm A Halcrow, Judith A K Howard

Affiliations

  1. Chemistry Department, Durham University, South Road, Durham DH1 3LE, UK.

PMID: 14734843 DOI: 10.1107/S0108768103027897

Abstract

The crystal structure of the iron(II) spin-crossover compound [Fe(C(10)H(8)N(6))(2)](ClO(4))(2) in the high-spin state has been solved from powder X-ray diffraction data using the DASH program and refined using Rietveld refinement. The thermal spin transition has been monitored by following the change in unit-cell parameters with temperature. The title compound has been found to undergo a crystallographic phase change, involving a doubling of the crystallographic a axis, on undergoing the spin transition.

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