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Johnson MD, Hornstein BJ. The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines. Inorg Chem. 2003;42(21):6923-8doi: 10.1021/ic020705x.
Johnson, M. D., & Hornstein, B. J. (2003). The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines. Inorganic chemistry, 42(21), 6923-8. https://doi.org/10.1021/ic020705x
Johnson, Michael D, and Hornstein, Brooks J. "The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines." Inorganic chemistry vol. 42,21 (2003): 6923-8. doi: https://doi.org/10.1021/ic020705x
Johnson MD, Hornstein BJ. The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines. Inorg Chem. 2003 Oct 20;42(21):6923-8. doi: 10.1021/ic020705x. PMID: 14552644.
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Inorg Chem. 2003 Oct 20;42(21):6923-8. doi: 10.1021/ic020705x.

The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines.

Inorganic chemistry

Michael D Johnson, Brooks J Hornstein

Affiliations

  1. Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, USA. [email protected]

PMID: 14552644 DOI: 10.1021/ic020705x

Abstract

Aqueous solutions of potassium ferrate(VI) cleanly and rapidly oxidize hydroxylamine to nitrous oxide, N-methylhydroxylamine to nitrosomethane, N-phenylhydroxylamine to nitrosobenzene, and O-methylhydroxylamine to methanol and nitrogen. The kinetics show first-order behavior with respect to each reactant and a two term component representing acid dependent and independent pathways. A general mechanism involving intermediate formation coupled with a two-electron oxidation is proposed.

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