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Chem Commun (Camb). 2003 Sep 21;(18):2344-5. doi: 10.1039/b307160j.

The first Pd(II) complex of a non-heteroatom stabilised carbene ligand.

Chemical communications (Cambridge, England)

Martin Bröring, Carsten D Brandt, Sascha Stellwag

Affiliations

  1. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany. [email protected]

PMID: 14518906 DOI: 10.1039/b307160j

Abstract

Di(p-tolyl)diazomethane reacts with the tripyrrinate TrpyPdOAc(F) 1 after activation with NaBAr(F) to yield the first stable Pd(II) complex 2 of a non-Arduengo type carbene ligand, which could be characterised by X-ray crystallography.

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