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Menger FM, Galloway AL, Musaev DG. Relationship between rate and distance. Chem Commun (Camb). 2003;(18):2370-1doi: 10.1039/b306342a.
Menger, F. M., Galloway, A. L., & Musaev, D. G. (2003). Relationship between rate and distance. Chemical communications (Cambridge, England), (18), 2370-1. https://doi.org/10.1039/b306342a
Menger, Fredric M, et al. "Relationship between rate and distance." Chemical communications (Cambridge, England) vol. ,18 (2003): 2370-1. doi: https://doi.org/10.1039/b306342a
Menger FM, Galloway AL, Musaev DG. Relationship between rate and distance. Chem Commun (Camb). 2003 Sep 21;(18):2370-1. doi: 10.1039/b306342a. PMID: 14518919.
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Chem Commun (Camb). 2003 Sep 21;(18):2370-1. doi: 10.1039/b306342a.

Relationship between rate and distance.

Chemical communications (Cambridge, England)

Fredric M Menger, Ashley L Galloway, Djamaladdin G Musaev

Affiliations

  1. Department of Chemistry, Emory University, Atlanta, GA, USA. [email protected]

PMID: 14518919 DOI: 10.1039/b306342a

Abstract

The activation energies for four Smiles reactions vary with the distance squared between the nucleophilic and electrophilic atoms (consistent with theoretical considerations and pertinent to organic and enzymatic catalyses).

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