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Phys Rev Lett. 2003 Dec 19;91(25):257601. doi: 10.1103/PhysRevLett.91.257601. Epub 2003 Dec 18.

Ferroelectricity in barium titanate quantum dots and wires.

Physical review letters

Huaxiang Fu, L Bellaiche

Affiliations

  1. Department of Physics, University of Arkansas, Fayetteville, Arkansas 72701, USA.

PMID: 14754156 DOI: 10.1103/PhysRevLett.91.257601

Abstract

Properties of BaTiO3 colloidal quantum dots and wires are simulated using a first-principles-based approach. Large atomic off-center displacements (that are robust against capping matrix materials) are found to exist in very small (<5 nm) dots. We further determine the size dependences of electrical and electromechanical responses in the studied nanostructures, as well as provide microscopic understanding of these responses.

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