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J Am Chem Soc. 2004 Feb 18;126(6):1652-3. doi: 10.1021/ja038383z.

Large parity violation effects in the vibrational spectrum of organometallic compounds.

Journal of the American Chemical Society

Peter Schwerdtfeger, Radovan Bast

Affiliations

  1. Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand. [email protected]

PMID: 14871094 DOI: 10.1021/ja038383z

Abstract

Large parity violation effects of the order of 1 Hz are predicted for the vibrational spectrum of two organometallic species, Os(eta5-C5H5)(=CCl2)Cl(PH3) and Re(eta5-Cp*)(=O)(CH3)Cl. It should therefore be possible to detect such effects in molecules by high-resolution spectroscopy for the first time.

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