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Lammel G. Sensitive method for the determination of different S(IV) species in cloud and fog water. Anal Bioanal Chem. 1996;356(1):107-8doi: 10.1007/s0021663560107.
Lammel, G. (1996). Sensitive method for the determination of different S(IV) species in cloud and fog water. Analytical and bioanalytical chemistry, 356(1), 107-8. https://doi.org/10.1007/s0021663560107
Lammel, G. "Sensitive method for the determination of different S(IV) species in cloud and fog water." Analytical and bioanalytical chemistry vol. 356,1 (1996): 107-8. doi: https://doi.org/10.1007/s0021663560107
Lammel G. Sensitive method for the determination of different S(IV) species in cloud and fog water. Anal Bioanal Chem. 1996 Aug;356(1):107-8. doi: 10.1007/s0021663560107. PMID: 15048380.
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Anal Bioanal Chem. 1996 Aug;356(1):107-8. doi: 10.1007/s0021663560107.

Sensitive method for the determination of different S(IV) species in cloud and fog water.

Analytical and bioanalytical chemistry

G Lammel

Affiliations

  1. Forschungszentrum Karlsruhe, LAF I, Postfach 3640, D-76021, Karlsruhe, Germany.

PMID: 15048380 DOI: 10.1007/s0021663560107

Abstract

Suppressed ion chromatography has been applied to the determination of S(IV) species in cloud and fog water in the range 0.012-2.4 mg S(IV)-S/L. The samples have been preserved prior to storage and S(IV) species have been determined as hydroxy methanesulfonate (HMS) together with the low molecular weight carboxylic acid anions, formate and acetate. Samples have been divided and treated differently such that total S(IV) as well as the non-oxidizable fraction of S(IV) (as given by the reactivity with H(2)O(2), added in surplus) could be determined. The difference between the two corresponds to the S(IV) fraction subjected to oxididation, which is of paramount interest in cloud and fogwater chemistry.

References

  1. Science. 1986 Jan 17;231(4735):247-9 - PubMed

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