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Rebelo SL, Simões MM, Neves MG, et al. An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins. Chem Commun (Camb). 2004;(5):608-9doi: 10.1039/b313683c.
Rebelo, S. L., Simões, M. M., Neves, M. G., Silva, A. M., & Cavaleiro, J. A. (2004). An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins. Chemical communications (Cambridge, England), (5), 608-9. https://doi.org/10.1039/b313683c
Rebelo, Susana L H, et al. "An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins." Chemical communications (Cambridge, England) vol. ,5 (2004): 608-9. doi: https://doi.org/10.1039/b313683c
Rebelo SL, Simões MM, Neves MG, Silva AM, Cavaleiro JA. An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins. Chem Commun (Camb). 2004 Mar 07;(5):608-9. doi: 10.1039/b313683c. Epub 2004 Jan 27. PMID: 14973631.
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Chem Commun (Camb). 2004 Mar 07;(5):608-9. doi: 10.1039/b313683c. Epub 2004 Jan 27.

An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins.

Chemical communications (Cambridge, England)

Susana L H Rebelo, Mário M Q Simões, M Graça P M S Neves, Artur M S Silva, José A S Cavaleiro

Affiliations

  1. Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.

PMID: 14973631 DOI: 10.1039/b313683c

Abstract

Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn(III) porphyrins [Mn(TDCPP)Cl, Mn(beta NO(2)TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.

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