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Dalton Trans. 2004 Apr 21;(8):1113-4. doi: 10.1039/b402718c. Epub 2004 Mar 19.

Poly(guanidyl)silanes as a new class of chelating, N-based ligand.

Dalton transactions (Cambridge, England : 2003)

Sarah H Oakley, Martyn P Coles, Peter B Hitchcock

Affiliations

  1. The Chemistry Department, University of Sussex, Falmer, Brighton, BN1 9QJ, UK.

PMID: 15252647 DOI: 10.1039/b402718c

Abstract

The series of poly(guanidyl)silanes RnSi[hpp](4-n) [hpp = 1,3,4,6,7,8-hexahydro-2Hpyrimido[1,2-a]pyrimidinate; R = Me, n= 1, 2; R = Ph, n= 1] have been synthesised and their coordination behaviour at copper(I) halides investigated.

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