Display options
Cite
Penel G, Leroy G, Rey C, et al. Infrared and Raman microspectrometry study of fluor-fluor-hydroxy and hydroxy-apatite powders. J Mater Sci Mater Med. 1997;8(5):271-6doi: 10.1023/a:1018504126866.
Penel, G., Leroy, G., Rey, C., Sombret, B., Huvenne, J. P., & Bres, E. (1997). Infrared and Raman microspectrometry study of fluor-fluor-hydroxy and hydroxy-apatite powders. Journal of materials science. Materials in medicine, 8(5), 271-6. https://doi.org/10.1023/a:1018504126866
Penel, G, et al. "Infrared and Raman microspectrometry study of fluor-fluor-hydroxy and hydroxy-apatite powders." Journal of materials science. Materials in medicine vol. 8,5 (1997): 271-6. doi: https://doi.org/10.1023/a:1018504126866
Penel G, Leroy G, Rey C, Sombret B, Huvenne JP, Bres E. Infrared and Raman microspectrometry study of fluor-fluor-hydroxy and hydroxy-apatite powders. J Mater Sci Mater Med. 1997 May;8(5):271-6. doi: 10.1023/a:1018504126866. PMID: 15348748.
Copy Download .nbib Format: NLM
Share it on

J Mater Sci Mater Med. 1997 May;8(5):271-6. doi: 10.1023/a:1018504126866.

Infrared and Raman microspectrometry study of fluor-fluor-hydroxy and hydroxy-apatite powders.

Journal of materials science. Materials in medicine

G Penel, G Leroy, C Rey, B Sombret, J P Huvenne, E Bres

Affiliations

  1. Laboratoire d'Anatomie bucco-dentaire, Université de Lille II, UFR de Chirurgie-Dentaire, France.

PMID: 15348748 DOI: 10.1023/a:1018504126866

Abstract

Visible Raman and infrared microspectrometry studies performed on fluorapatite and hydroxyapatite powders have shown similar results. Small modifications of the nu2 and nu4 PO(3-)4 tetrahedra bending modes are observed. A small frequency shift of the nu1 mode and modifications on the nu3 mode region accompanied with a simplification of the hydroxyapatite and fluorapatite respective spectra from seven to four bands were observed. A broad and weak band which could be attributed to the Ca-F bond is detected at 311 cm(-1) on the Raman fluorapatite spectra. The phosphate vibration modes are little disturbed by fluoride substitution. This could indicate that phosphate groups interact strongly between themselves and weakly with substituted atoms (i.e. hydroxyle and fluoride atoms). Whatever crystallographic model is considered, the number of bands observed is always lower than the number of calculated ones, even for hydroxyapatite, whose symmetry is lower than that of fluorapatite.

References

  1. Calcif Tissue Int. 1990 Jun;46(6):384-94 - PubMed
  2. Arch Oral Biol. 1966 May;11(5):477-92 - PubMed
  3. Nature. 1964 Dec 12;204:1050-2 - PubMed
  4. J Dent Res. 1994 Nov;73(11):1703-10 - PubMed
  5. Arch Oral Biol. 1974 Nov;19(11):995-06 - PubMed
  6. Calcif Tissue Int. 1991 Dec;49(6):383-8 - PubMed

Publication Types