J Chem Phys. 2004 Nov 08;121(18):9066-76. doi: 10.1063/1.1805515.

Orientational structures in confined smectic-C domains in Langmuir monolayers.

The Journal of chemical physics

R Reigada, E Abad, J Crusats, J Claret, J Ignés-Mullol, F Sagués

PMID: 15527373 DOI: 10.1063/1.1805515

Abstract

Droplet smectic-C domains in films of surfactant molecules exhibit different orientational textures. For these systems we formulate a kinetic model based on a free energy functional containing bulk (elastic) and surface interactions. Numerical simulations for the corresponding relaxational equation show the existence of two different equilibrium configurations with a centered defect. In particular, when the elastic terms dominate, bend-shaped textures appear, whereas for strong boundary effects mixed bend/splay conformations are displayed. A variational analysis for the free energy functional confirms the validity of the above numerical results. The stability of textures with centered defects with respect to the formation of periferic defects (boojums) is also discussed qualitatively. The above theoretical predictions are compared with experimental results from Brewster angle microscopy imaging of azobenzene Langmuir monolayers.

Copyright 2004 American Institute of Physics.

Publication Types

• Journal Article