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Chem Commun (Camb). 2004 Dec 07;(23):2720-1. doi: 10.1039/b409451d. Epub 2004 Oct 08.

Manipulation of the stereochemical outcome and product distribution in the Henry reaction using CO2 pressure.

Chemical communications (Cambridge, England)

Andrew J Parratt, Dave J Adams, Anthony A Clifford, Christopher M Rayner

Affiliations

  1. Department of Chemistry, University of Leeds, Leeds LS2 9JT, UK.

PMID: 15568084 DOI: 10.1039/b409451d

Abstract

The rate and stereocontrol of the Henry reaction in the presence of CO(2) can be controlled simply by manipulation of CO(2) pressure, and can be understood by consideration of the kinetic and thermodynamic aspects of the reaction.

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