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Gabriele B, Mancuso R, Salerno G, et al. Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection - Pd(II)-catalysed heterocyclisation reaction leading to benzofurans. Chem Commun (Camb). 2004;(2):271-3doi: 10.1039/b413240h.
Gabriele, B., Mancuso, R., Salerno, G., & Veltri, L. (2005). Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection - Pd(II)-catalysed heterocyclisation reaction leading to benzofurans. Chemical communications (Cambridge, England), (2), 271-3. https://doi.org/10.1039/b413240h
Gabriele, Bartolo, et al. "Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection - Pd(II)-catalysed heterocyclisation reaction leading to benzofurans." Chemical communications (Cambridge, England) vol. ,2 (2005): 271-3. doi: https://doi.org/10.1039/b413240h
Gabriele B, Mancuso R, Salerno G, Veltri L. Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection - Pd(II)-catalysed heterocyclisation reaction leading to benzofurans. Chem Commun (Camb). 2005 Jan 14;(2):271-3. doi: 10.1039/b413240h. Epub 2004 Nov 12. PMID: 15724209.
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Chem Commun (Camb). 2005 Jan 14;(2):271-3. doi: 10.1039/b413240h. Epub 2004 Nov 12.

Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection - Pd(II)-catalysed heterocyclisation reaction leading to benzofurans.

Chemical communications (Cambridge, England)

Bartolo Gabriele, Raffaella Mancuso, Giuseppe Salerno, Lucia Veltri

Affiliations

  1. Dipartimento di Scienze Farmaceutiche, Universita della Calabria, 87036, Arcavacata di Rende (CS), Italy. [email protected]

PMID: 15724209 DOI: 10.1039/b413240h

Abstract

We report here the first example of "sequential homobimetallic catalysis": a transition metal catalyst with the metal in a certain oxidation state catalyses the deprotection of a functional group, which in situ undergoes a subsequent transformation catalysed by another complex of the same metal but in a different oxidation state.

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