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Djordjevic B, Schuster O, Schmidbaur H. A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules. Inorg Chem. 2005;44(3):673-6doi: 10.1021/ic048795o.
Djordjevic, B., Schuster, O., & Schmidbaur, H. (2005). A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules. Inorganic chemistry, 44(3), 673-6. https://doi.org/10.1021/ic048795o
Djordjevic, Bratislav, et al. "A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules." Inorganic chemistry vol. 44,3 (2005): 673-6. doi: https://doi.org/10.1021/ic048795o
Djordjevic B, Schuster O, Schmidbaur H. A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules. Inorg Chem. 2005 Feb 07;44(3):673-6. doi: 10.1021/ic048795o. PMID: 15679401.
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Inorg Chem. 2005 Feb 07;44(3):673-6. doi: 10.1021/ic048795o.

A cyclic hexamer of silver trifluoroacetate supported by four triphenylphosphine sulfide template molecules.

Inorganic chemistry

Bratislav Djordjevic, Oliver Schuster, Hubert Schmidbaur

Affiliations

  1. Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany.

PMID: 15679401 DOI: 10.1021/ic048795o

Abstract

Crystallization of silver trifluoroacetate from chloroform solutions containing triphenylphosphine sulfide affords a trigonal and a monoclinic form of a 6:4 complex {[CF3C(O)OAg]6(Ph3PS)4} of C2 symmetry with different amounts of chloroform in the crystals. With the Ph3PS components as template molecules, the CF3C(O)OAg units are assembled to form a 6-membered metallacycle codetermined by metallophilic bonding and enclosed by a 24-membered ring [AgOCO]6. A complex of the type [LAgOC(O)CF3]2, with L representing the isocyanide ligand pTolSO2CH2NC, has been shown to have a conventional bicyclic structure with three-coordinate silver atoms engaged in transannular metallophilic interactions.

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