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Heinicke J, Peulecke N, Karaghiosoff K, et al. 2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate). Inorg Chem. 2005;44(7):2137-9doi: 10.1021/ic0484304.
Heinicke, J., Peulecke, N., Karaghiosoff, K., & Mayer, P. (2005). 2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate). Inorganic chemistry, 44(7), 2137-9. https://doi.org/10.1021/ic0484304
Heinicke, Joachim, et al. "2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate)." Inorganic chemistry vol. 44,7 (2005): 2137-9. doi: https://doi.org/10.1021/ic0484304
Heinicke J, Peulecke N, Karaghiosoff K, Mayer P. 2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate). Inorg Chem. 2005 Apr 04;44(7):2137-9. doi: 10.1021/ic0484304. PMID: 15792446.
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Inorg Chem. 2005 Apr 04;44(7):2137-9. doi: 10.1021/ic0484304.

2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate).

Inorganic chemistry

Joachim Heinicke, Normen Peulecke, Konstantin Karaghiosoff, Peter Mayer

Affiliations

  1. Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universität Greifswald, D-17487 Greifswald, Germany. [email protected]

PMID: 15792446 DOI: 10.1021/ic0484304

Abstract

A novel linear trinuclear mu-O-bridging 2-phosphinophenolate nickel(II) complex with fac-tris(P(intersection)O- chelates) in the terminal positions and the three oxygen atoms each facing the central nickel(II) cation was synthesized and structurally characterized by X-ray crystallography. To the best of our knowledge, this is the first example of an octahedral Ni(II) tris(P(intersection)O- chelate).

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