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Teare DO, Schofield WC, Garrod RP, et al. Rapid polymer brush growth by TEMPO-mediated controlled free-radical polymerization from swollen plasma deposited poly(maleic anhydride) initiator surfaces. Langmuir. 2005;21(23):10818-24doi: 10.1021/la051566+.
Teare, D. O., Schofield, W. C., Garrod, R. P., & Badyal, J. P. (2005). Rapid polymer brush growth by TEMPO-mediated controlled free-radical polymerization from swollen plasma deposited poly(maleic anhydride) initiator surfaces. Langmuir : the ACS journal of surfaces and colloids, 21(23), 10818-24. https://doi.org/10.1021/la051566+
Teare, D O H, et al. "Rapid polymer brush growth by TEMPO-mediated controlled free-radical polymerization from swollen plasma deposited poly(maleic anhydride) initiator surfaces." Langmuir : the ACS journal of surfaces and colloids vol. 21,23 (2005): 10818-24. doi: https://doi.org/10.1021/la051566+
Teare DO, Schofield WC, Garrod RP, Badyal JP. Rapid polymer brush growth by TEMPO-mediated controlled free-radical polymerization from swollen plasma deposited poly(maleic anhydride) initiator surfaces. Langmuir. 2005 Nov 08;21(23):10818-24. doi: 10.1021/la051566+. PMID: 16262358.
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Langmuir. 2005 Nov 08;21(23):10818-24. doi: 10.1021/la051566+.

Rapid polymer brush growth by TEMPO-mediated controlled free-radical polymerization from swollen plasma deposited poly(maleic anhydride) initiator surfaces.

Langmuir : the ACS journal of surfaces and colloids

D O H Teare, W C E Schofield, R P Garrod, J P S Badyal

Affiliations

  1. Department of Chemistry, Science Laboratories, Durham University, England, UK.

PMID: 16262358 DOI: 10.1021/la051566+

Abstract

Pulsed plasma-chemical deposition of poly(maleic anhydride) is shown to be a substrate-independent method for functionalizing solid surfaces with initiator sites for nitroxide-mediated controlled free-radical graft polymerization. Swelling of the initiator film via aminolysis can lead to grafted polymer brushes that are 1 order of magnitude thicker than those obtained by existing methods on solid surfaces.

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