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Winnewisser BP, Winnewisser M, Medvedev IR, et al. Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS. Phys Rev Lett. 2005;95(24):243002doi: 10.1103/PhysRevLett.95.243002.
Winnewisser, B. P., Winnewisser, M., Medvedev, I. R., Behnke, M., De Lucia, F. C., Ross, S. C., & Koput, J. (2005). Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS. Physical review letters, 95(24), 243002. https://doi.org/10.1103/PhysRevLett.95.243002
Winnewisser, Brenda P, et al. "Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS." Physical review letters vol. 95,24 (2005): 243002. doi: https://doi.org/10.1103/PhysRevLett.95.243002
Winnewisser BP, Winnewisser M, Medvedev IR, Behnke M, De Lucia FC, Ross SC, Koput J. Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS. Phys Rev Lett. 2005 Dec 09;95(24):243002. doi: 10.1103/PhysRevLett.95.243002. Epub 2005 Dec 05. PMID: 16384372.
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Phys Rev Lett. 2005 Dec 09;95(24):243002. doi: 10.1103/PhysRevLett.95.243002. Epub 2005 Dec 05.

Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS.

Physical review letters

Brenda P Winnewisser, Manfred Winnewisser, Ivan R Medvedev, Markus Behnke, Frank C De Lucia, Stephen C Ross, Jacek Koput

Affiliations

  1. Department of Physics, The Ohio State University, Columbus, Ohio 43210-1106, USA.

PMID: 16384372 DOI: 10.1103/PhysRevLett.95.243002

Abstract

We have made energy-momentum maps for the experimental end-over-end rotational energy and the two-dimensional bending vibrational energy, both of which confirm the dominating effects of nontrivial quantum monodromy in cyanogen isothiocyanate. Accidental resonances in the rotational spectra yield accurate intervals between bending states.

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