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Chem Commun (Camb). 2006 Jan 21;(3):296-8. doi: 10.1039/b512838b. Epub 2005 Nov 22.

Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles.

Chemical communications (Cambridge, England)

Audrey Nowicki, Yong Zhang, Bastien Léger, Jean-Paul Rolland, Hervé Bricout, Eric Monflier, Alain Roucoux

Affiliations

  1. UMR CNRS 6052, Synthèses et Activations de Biomolécules, Ecole Nationale Supérieure de Chimie de Rennes, Institut de Chimie de Rennes, Avenue du Général Leclerc, 35700, Rennes, France.

PMID: 16391739 DOI: 10.1039/b512838b

Abstract

Efficient chemoselectivities have been obtained in the hydrogenation of benzene derivatives under biphasic liquid-liquid conditions using Ru(0) nanoparticles stabilized and controlled by the relevant choice of cavity and methylation degree of cyclodextrins.

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