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Talyzin AV, Tsybin YO, Peera AA, et al. Synthesis of C59Hx and C58Hx fullerenes stabilized by hydrogen. J Phys Chem B. 2005;109(12):5403-5doi: 10.1021/jp050364j.
Talyzin, A. V., Tsybin, Y. O., Peera, A. A., Schaub, T. M., Marshall, A. G., Sundqvist, B., Mauron, P., Züttel, A., & Billups, W. E. (2005). Synthesis of C59Hx and C58Hx fullerenes stabilized by hydrogen. The journal of physical chemistry. B, 109(12), 5403-5. https://doi.org/10.1021/jp050364j
Talyzin, Alexandr V, et al. "Synthesis of C59Hx and C58Hx fullerenes stabilized by hydrogen." The journal of physical chemistry. B vol. 109,12 (2005): 5403-5. doi: https://doi.org/10.1021/jp050364j
Talyzin AV, Tsybin YO, Peera AA, Schaub TM, Marshall AG, Sundqvist B, Mauron P, Züttel A, Billups WE. Synthesis of C59Hx and C58Hx fullerenes stabilized by hydrogen. J Phys Chem B. 2005 Mar 31;109(12):5403-5. doi: 10.1021/jp050364j. PMID: 16851570.
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J Phys Chem B. 2005 Mar 31;109(12):5403-5. doi: 10.1021/jp050364j.

Synthesis of C59Hx and C58Hx fullerenes stabilized by hydrogen.

The journal of physical chemistry. B

Alexandr V Talyzin, Yury O Tsybin, Asghar A Peera, Tanner M Schaub, Alan G Marshall, Bertil Sundqvist, Philippe Mauron, Andreas Züttel, W E Billups

Affiliations

  1. Department of Physics, Umeå University, 901 87 Umeå, Sweden. [email protected]

PMID: 16851570 DOI: 10.1021/jp050364j

Abstract

Prolonged hydrogenation of C(60) molecules by reaction with H(2) at elevated temperature and pressure results in fragmentation and collapse of the fullerene cage structure. However, fragments can be preserved by immediate termination of dangling bonds by hydrogen. Here we demonstrate that not only fullerene fragments but also hydrogenated fragmented fullerenes (e.g., C(58)H(40) and C(59)H(40)) can be synthesized in bulk amount by high-temperature hydrogenation of C(60). We confirm successful synthesis of these species by matrix-assisted laser desorption ionization time-of-flight mass spectrometry and complete speciation of the resultant complex fullerene mixtures by high-resolution field desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry.

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