Chemistry. 2006 Sep 18;12(27):7151-60. doi: 10.1002/chem.200600037.

Effect of polarity and structural design on molecular photorefractive properties of heteroaromatic-based push-pull dyes.

Chemistry (Weinheim an der Bergstrasse, Germany)

Graziano Archetti, Alessandro Abbotto, Rüdiger Wortmann

PMID: 16823780 DOI: 10.1002/chem.200600037

Abstract

A combined experimental (optical and electro-optical absorption measurements) and computational (ab initio RHF and DFT) approach has been used to investigate the molecular low- and high-T(g) photorefractive (PR) performances of neutral and zwitterionic heteroaromatic dipolar chromophores in terms of structural and solvent-polarity effects. We have found that the nature of the building units (donor, acceptor, and spacer) and the polarity of the surrounding medium strongly affect all the relevant ground-state and nonlinear optical properties involved in the PR activity, that is, the dipole moment, the polarizability anisotropy, and first hyperpolarizability of the electronic ground-state. The variation of these properties is in turn transferred to molecular low- and high-T(g) PR figures of merit. It is shown that PR molecular performance not only relies on a proper choice of structural components but varies by orders of magnitude as a function of the medium polarity, and this suggests that a combination of molecular design and host-matrix engineering is required for optimized performances of PR materials.

Publication Types

• Journal Article