Display options
Cite
Kim A, Filler MA, Kim S, et al. Ethylenediamine on Ge(100)-2 x 1: the role of interdimer interactions. J Phys Chem B. 2005;109(42):19817-22doi: 10.1021/jp054340o.
Kim, A., Filler, M. A., Kim, S., & Bent, S. F. (2005). Ethylenediamine on Ge(100)-2 x 1: the role of interdimer interactions. The journal of physical chemistry. B, 109(42), 19817-22. https://doi.org/10.1021/jp054340o
Kim, Ansoon, et al. "Ethylenediamine on Ge(100)-2 x 1: the role of interdimer interactions." The journal of physical chemistry. B vol. 109,42 (2005): 19817-22. doi: https://doi.org/10.1021/jp054340o
Kim A, Filler MA, Kim S, Bent SF. Ethylenediamine on Ge(100)-2 x 1: the role of interdimer interactions. J Phys Chem B. 2005 Oct 27;109(42):19817-22. doi: 10.1021/jp054340o. PMID: 16853562.
Copy Download .nbib Format: NLM
Share it on

J Phys Chem B. 2005 Oct 27;109(42):19817-22. doi: 10.1021/jp054340o.

Ethylenediamine on Ge(100)-2 x 1: the role of interdimer interactions.

The journal of physical chemistry. B

Ansoon Kim, Michael A Filler, Sehun Kim, Stacey F Bent

Affiliations

  1. Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea.

PMID: 16853562 DOI: 10.1021/jp054340o

Abstract

We have investigated the reaction of the bifunctional molecule ethylenediamine on Ge(100)-2 x 1 using multiple internal reflection Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and density functional theory calculations. Ethylenediamine exhibits different adsorption behavior than simple methylamines on the Ge(100)-2 x 1 surface. At low coverages, ethylenediamine undergoes dissociative chemisorption via an interdimer dual N-H dissociation reaction. As coverage increases, the N-H dissociation reaction is inhibited and formation of a Ge-N dative-bonded structure dominates.

Publication Types