Display options
Cite
Ushak S, Spodine E, Le Fur E, et al. Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8. Synthesis, structure, and magnetic properties. Inorg Chem. 2006;45(14):5393-8doi: 10.1021/ic060152g.
Ushak, S., Spodine, E., Le Fur, E., Venegas-Yazigi, D., Pivan, J. Y., Schnelle, W., Cardoso-Gil, R., & Kniep, R. (2006). Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8. Synthesis, structure, and magnetic properties. Inorganic chemistry, 45(14), 5393-8. https://doi.org/10.1021/ic060152g
Ushak, Svetlana, et al. "Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8. Synthesis, structure, and magnetic properties." Inorganic chemistry vol. 45,14 (2006): 5393-8. doi: https://doi.org/10.1021/ic060152g
Ushak S, Spodine E, Le Fur E, Venegas-Yazigi D, Pivan JY, Schnelle W, Cardoso-Gil R, Kniep R. Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8. Synthesis, structure, and magnetic properties. Inorg Chem. 2006 Jul 10;45(14):5393-8. doi: 10.1021/ic060152g. PMID: 16813402.
Copy Download .nbib Format: NLM
Share it on

Inorg Chem. 2006 Jul 10;45(14):5393-8. doi: 10.1021/ic060152g.

Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8. Synthesis, structure, and magnetic properties.

Inorganic chemistry

Svetlana Ushak, Evgenia Spodine, Eric Le Fur, Diego Venegas-Yazigi, Jean-Yves Pivan, Walter Schnelle, Raul Cardoso-Gil, Rüdiger Kniep

Affiliations

  1. Centro para la Investigación Interdisciplinaria Avanzada en Ciencia de los Materiales, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago, Chile.

PMID: 16813402 DOI: 10.1021/ic060152g

Abstract

Two new hybrid organic/inorganic copper oxovanadium diphosphonates [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O (1) and [(Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8 (2) have been obtained by hydrothermal synthesis. The compounds are monoclinic, and they crystallize in the space group P2(1)/n with cell parameters of a = 11.788(2) A, b = 17.887(3) A, c = 14.158(2) A, and beta = 93.99(0) degrees and in the space group C2/c with cell parameters of a = 11.025(1) A, b = 18.664(2) A, c = 15.054(2) A, and beta = 90.06(0) degrees, respectively. Both compounds present two-dimensional frameworks built up from infinite chains of corner-sharing vanadium tetrahedra and diphosphonate groups connected by copper tetramers for (1) and copper dimers for (2). The remarkable feature of (2) is the encapsulation of propane molecules, stabilized by strong hydrogen bonding between the layers. The magnetic properties of the compounds have been investigated showing antiferromagnetic coupling with Tmax = 64 K for (1) and Curie-like paramagnetic behavior for (2).

Publication Types