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Acta Crystallogr C. 2006 Dec;62:m574-6. doi: 10.1107/S0108270106039734. Epub 2006 Nov 10.

Aqua(2,2'-bipyridyl)chloronitratocopper(II).

Acta crystallographica. Section C, Crystal structure communications

Sujittra Youngme, Jaturong Phatchimkun, Narongsak Chaichit

Affiliations

  1. Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand. [email protected]

PMID: 17148888 DOI: 10.1107/S0108270106039734

Abstract

In a new hydrogen-bonded three-dimensional complex, [CuCl(NO3)(C10H8N2)(H2O)], the Cu atom has an elongated tetragonal octahedral environment, with two 2,2'-bipyridyl N atoms, one nitrate O atom and one Cl atom forming the equatorial plane, and a second O atom of the nitrate anion and a water molecule in the axial positions. The complex molecules are linked to form a three-dimensional supramolecular array by hydrogen-bonding interactions both between the water O atom and nitrate O atoms, and between the water O atom and the Cl atom of a neighboring molecule.

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