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Chem Commun (Camb). 2007 Jan 28;(4):374-6. doi: 10.1039/b611623j. Epub 2006 Dec 18.

Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2).

Chemical communications (Cambridge, England)

Anna S Pimenova, Andrey A Kozlov, Alexey A Goryunkov, Vitaliy Yu Markov, Pavel A Khavrel, Stanislav M Avdoshenko, Ilya N Ioffe, Sergey G Sakharov, Sergey I Troyanov, Lev N Sidorov

Affiliations

  1. Chemistry Department, Moscow State University, Moscow 119992, Russia.

PMID: 17220975 DOI: 10.1039/b611623j

Abstract

Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1-3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.

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