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Brewer CT, Brewer G, Butcher RJ, et al. Synthesis and characterization of a spin crossover iron(II)-iron(III) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and pi-pi interactions. Dalton Trans. 2006;(3):295-8doi: 10.1039/b613282k.
Brewer, C. T., Brewer, G., Butcher, R. J., Carpenter, E. E., Schmiedekamp, A. M., & Viragh, C. (2007). Synthesis and characterization of a spin crossover iron(II)-iron(III) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and pi-pi interactions. Dalton transactions (Cambridge, England : 2003), (3), 295-8. https://doi.org/10.1039/b613282k
Brewer, Cynthia T, et al. "Synthesis and characterization of a spin crossover iron(II)-iron(III) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and pi-pi interactions." Dalton transactions (Cambridge, England : 2003) vol. ,3 (2007): 295-8. doi: https://doi.org/10.1039/b613282k
Brewer CT, Brewer G, Butcher RJ, Carpenter EE, Schmiedekamp AM, Viragh C. Synthesis and characterization of a spin crossover iron(II)-iron(III) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and pi-pi interactions. Dalton Trans. 2007 Jan 21;(3):295-8. doi: 10.1039/b613282k. Epub 2006 Nov 20. PMID: 17200748.
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Dalton Trans. 2007 Jan 21;(3):295-8. doi: 10.1039/b613282k. Epub 2006 Nov 20.

Synthesis and characterization of a spin crossover iron(II)-iron(III) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and pi-pi interactions.

Dalton transactions (Cambridge, England : 2003)

Cynthia T Brewer, Greg Brewer, Ray J Butcher, Everett E Carpenter, Ann M Schmiedekamp, Carol Viragh

Affiliations

  1. The Catholic University of America, Washington, DC 20064, USA. [email protected]

PMID: 17200748 DOI: 10.1039/b613282k

Abstract

Reaction of iron(II) and the 3 : 1 Schiff base condensate of 5-methylpyrazole-3-carboxaldehyde and tris(2-aminoethyl)amine in air gives a pseudo-dimer complex with a triple helix structure made of Delta-Delta and Lambda-Lambda pairings of spin crossover iron(II) and low spin iron(III) cations that are held together by three pi-pi and hydrogen bonding interactions.

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