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Angew Chem Int Ed Engl. 2007;46(26):4832-87. doi: 10.1002/anie.200604203.

Discotic liquid crystals: from tailor-made synthesis to plastic electronics.

Angewandte Chemie (International ed. in English)

Sabine Laschat, Angelika Baro, Nelli Steinke, Frank Giesselmann, Constanze Hägele, Giusy Scalia, Roxana Judele, Elisabeth Kapatsina, Sven Sauer, Alina Schreivogel, Martin Tosoni

Affiliations

  1. Institut für Organische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany. [email protected]

PMID: 17568461 DOI: 10.1002/anie.200604203

Abstract

Most associate liquid crystals with their everyday use in laptop computers, mobile phones, digital cameras, and other electronic devices. However, in contrast to their rodlike (calamitic) counterparts, first described in 1907 by Vorländer, disklike (discotic, columnar) liquid crystals, which were discovered in 1977 by Chandrasekhar et al., offer further applications as a result of their orientation in the columnar mesophase, making them ideal candidates for molecular wires in various optical and electronic devices such as photocopiers, laser printers, photovoltaic cells, light-emitting diodes, field-effect transistors, and holographic data storage. Beginning with an overview of the various mesophases and characterization methods, this Review will focus on the major classes of columnar mesogens rather than presenting a library of columnar liquid crystals. Emphasis will be given to efficient synthetic procedures, and relevant mesomorphic and physical properties. Finally, some applications and perspectives in materials science and molecular electronics will be discussed.

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