Display options
Cite
Diestler DJ, Schoen M, Cushman JH. On the thermodynamic stability of confined thin films under shear. Science. 1993;262(5133):545-7doi: 10.1126/science.262.5133.545.
Diestler, D. J., Schoen, M., & Cushman, J. H. (1993). On the thermodynamic stability of confined thin films under shear. Science (New York, N.Y.), 262(5133), 545-7. https://doi.org/10.1126/science.262.5133.545
Diestler, D J, et al. "On the thermodynamic stability of confined thin films under shear." Science (New York, N.Y.) vol. 262,5133 (1993): 545-7. doi: https://doi.org/10.1126/science.262.5133.545
Diestler DJ, Schoen M, Cushman JH. On the thermodynamic stability of confined thin films under shear. Science. 1993 Oct 22;262(5133):545-7. doi: 10.1126/science.262.5133.545. PMID: 17733235.
Copy Download .nbib Format: NLM
Share it on

Science. 1993 Oct 22;262(5133):545-7. doi: 10.1126/science.262.5133.545.

On the thermodynamic stability of confined thin films under shear.

Science (New York, N.Y.)

D J Diestler, M Schoen, J H Cushman

PMID: 17733235 DOI: 10.1126/science.262.5133.545

Abstract

Thin films of monatomic fluid constrained between two plane-parallel structured solid walls have been modeled by Monte Carlo simulation under conditions (fixed temperature, chemical potential, and normal stress or load) prevailing in high-precision measurements of surface forces. Several states of the film, corresponding to different numbers of layers of fluid parallel with the walls, are generally consistent with these conditions, but only one is thermodynamically stable; the others are metastable. When the walls are properly aligned, epitaxial solid phases are stable. These melt under shear, eventually becoming metastable, whereupon a drainage (or imbibition) transition occurs, leading to a stable phase with fewer (or more) layers.

Publication Types