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Dalton Trans. 2008 Apr 21;(15):1976-8. doi: 10.1039/b719012c. Epub 2008 Feb 18.

Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene.

Dalton transactions (Cambridge, England : 2003)

Jamie J R Frew, Matthew L Clarke, Ulrich Mayer, Hendrik Van Rensburg, Robert P Tooze

Affiliations

  1. School of Chemistry, University of St Andrews, St. Andrews, Fife, UK KY16 9ST.

PMID: 18382772 DOI: 10.1039/b719012c

Abstract

Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

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