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Makoudi Y, Palmino F, Duverger E, et al. Nondestructive room-temperature adsorption of 2,4,6-tri(2'-thienyl)-1,3,5-triazine on a Si-B interface: high-resolution STM imaging and molecular modeling. Phys Rev Lett. 2008;100(7):076405doi: 10.1103/PhysRevLett.100.076405.
Makoudi, Y., Palmino, F., Duverger, E., Arab, M., Chérioux, F., Ramseyer, C., Therrien, B., Tschan, M. J., & Süss-Fink, G. (2008). Nondestructive room-temperature adsorption of 2,4,6-tri(2'-thienyl)-1,3,5-triazine on a Si-B interface: high-resolution STM imaging and molecular modeling. Physical review letters, 100(7), 076405. https://doi.org/10.1103/PhysRevLett.100.076405
Makoudi, Y, et al. "Nondestructive room-temperature adsorption of 2,4,6-tri(2'-thienyl)-1,3,5-triazine on a Si-B interface: high-resolution STM imaging and molecular modeling." Physical review letters vol. 100,7 (2008): 076405. doi: https://doi.org/10.1103/PhysRevLett.100.076405
Makoudi Y, Palmino F, Duverger E, Arab M, Chérioux F, Ramseyer C, Therrien B, Tschan MJ, Süss-Fink G. Nondestructive room-temperature adsorption of 2,4,6-tri(2'-thienyl)-1,3,5-triazine on a Si-B interface: high-resolution STM imaging and molecular modeling. Phys Rev Lett. 2008 Feb 22;100(7):076405. doi: 10.1103/PhysRevLett.100.076405. Epub 2008 Feb 22. PMID: 18352579.
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Phys Rev Lett. 2008 Feb 22;100(7):076405. doi: 10.1103/PhysRevLett.100.076405. Epub 2008 Feb 22.

Nondestructive room-temperature adsorption of 2,4,6-tri(2'-thienyl)-1,3,5-triazine on a Si-B interface: high-resolution STM imaging and molecular modeling.

Physical review letters

Y Makoudi, F Palmino, E Duverger, M Arab, F Chérioux, C Ramseyer, B Therrien, M J-L Tschan, G Süss-Fink

Affiliations

  1. Institut FEMTO-ST/LPMO, CNRS UMR 6174, 32 Avenue de l'Observatoire, F-25044 Besancon cedex, France.

PMID: 18352579 DOI: 10.1103/PhysRevLett.100.076405

Abstract

Organic nanostructures on semiconductors are currently investigated but the surfaces are known to interact strongly with molecules. To reduce the molecule-surface interaction, we used the Si(111)-B square root 3 x square root 3R30 degrees . Deposition of isolated 2,4,6-tri(2'-thienyl)-1,3,5-triazine, was achieved at room temperature without modification of their pi skeleton. This fascinating arrangement, observed by STM, has been validated by full density functional theory computations onto the entire system. The theoretical results give a clear explanation for the specific adsorption sites of molecules on the substrate.

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