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Appl Opt. 2001 Aug 01;40(22):3737-45. doi: 10.1364/ao.40.003737.

Imaging phase-separated domains in conducting polymer blend films with near-field scanning optical microscopy.

Applied optics

J Hwang, L S Goldner, A Karim, C Gettinger

PMID: 18360407 DOI: 10.1364/ao.40.003737

Abstract

We present high-resolution images with near-field scanning optical microscopy to study phase separation in polymer films of poly(styrene) and poly(3-octyl-thiophene). Transmission and transmitted fluorescence near-field scanning optical microscope images were taken for direct visualization of the intermediate steps of phase separation in a regime where small domain sizes prevent investigation by conventional microscopy. The interpretation of near-field data on samples with large or varying film thickness or topography are also discussed, and a method for recognizing topographically induced artifacts in a quantitative way is suggested.

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