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Fleet B, Jee RD. A.C. polarographic determination of unsaturation. Talanta. 1969;16(12):1561-9doi: 10.1016/0039-9140(69)80217-1.
Fleet, B., & Jee, R. D. (1969). A.C. polarographic determination of unsaturation. Talanta, 16(12), 1561-9. https://doi.org/10.1016/0039-9140(69)80217-1
Fleet, B, and Jee, R D. "A.C. polarographic determination of unsaturation." Talanta vol. 16,12 (1969): 1561-9. doi: https://doi.org/10.1016/0039-9140(69)80217-1
Fleet B, Jee RD. A.C. polarographic determination of unsaturation. Talanta. 1969 Dec;16(12):1561-9. doi: 10.1016/0039-9140(69)80217-1. PMID: 18960677.
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Talanta. 1969 Dec;16(12):1561-9. doi: 10.1016/0039-9140(69)80217-1.

A.C. polarographic determination of unsaturation.

Talanta

B Fleet, R D Jee

Affiliations

  1. Chemistry Department, Imperial College of Science and Technology, London. S.W.7., U.K.

PMID: 18960677 DOI: 10.1016/0039-9140(69)80217-1

Abstract

A wide range of olefins can be determined by a.c. polarography of their addition compounds with mercuric acetate. The first step in the reduction of these compounds is a reversible, one-electron process to form the organo-mercury radical and gives a well defined a.c. peak. The optimum conditions for the determination of a representative selection of olefins has been established.

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