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Ennis CP, Lane JR, Kjaergaard HG, et al. Identification of the water amidogen radical complex. J Am Chem Soc. 2009;131(4):1358-9doi: 10.1021/ja808109m.
Ennis, C. P., Lane, J. R., Kjaergaard, H. G., & McKinley, A. J. (2009). Identification of the water amidogen radical complex. Journal of the American Chemical Society, 131(4), 1358-9. https://doi.org/10.1021/ja808109m
Ennis, Courtney P, et al. "Identification of the water amidogen radical complex." Journal of the American Chemical Society vol. 131,4 (2009): 1358-9. doi: https://doi.org/10.1021/ja808109m
Ennis CP, Lane JR, Kjaergaard HG, McKinley AJ. Identification of the water amidogen radical complex. J Am Chem Soc. 2009 Feb 04;131(4):1358-9. doi: 10.1021/ja808109m. PMID: 19173661.
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J Am Chem Soc. 2009 Feb 04;131(4):1358-9. doi: 10.1021/ja808109m.

Identification of the water amidogen radical complex.

Journal of the American Chemical Society

Courtney P Ennis, Joseph R Lane, Henrik G Kjaergaard, Allan J McKinley

Affiliations

  1. Chemistry M313, School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 Australia.

PMID: 19173661 DOI: 10.1021/ja808109m

Abstract

The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

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