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Ganesamoorthy C, Balakrishna MS, Mague JT. Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra (phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions. Dalton Trans. 2009;(11):1984-90doi: 10.1039/b815849e.
Ganesamoorthy, C., Balakrishna, M. S., & Mague, J. T. (2009). Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra (phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions. Dalton transactions (Cambridge, England : 2003), (11), 1984-90. https://doi.org/10.1039/b815849e
Ganesamoorthy, Chelladurai, et al. "Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra (phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions." Dalton transactions (Cambridge, England : 2003) vol. ,11 (2009): 1984-90. doi: https://doi.org/10.1039/b815849e
Ganesamoorthy C, Balakrishna MS, Mague JT. Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra (phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions. Dalton Trans. 2009 Mar 21;(11):1984-90. doi: 10.1039/b815849e. Epub 2009 Jan 29. PMID: 19259568.
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Dalton Trans. 2009 Mar 21;(11):1984-90. doi: 10.1039/b815849e. Epub 2009 Jan 29.

Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra (phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions.

Dalton transactions (Cambridge, England : 2003)

Chelladurai Ganesamoorthy, Maravanji S Balakrishna, Joel T Mague

Affiliations

  1. Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India.

PMID: 19259568 DOI: 10.1039/b815849e

Abstract

The reactions of phenylene-1,4-diaminotetra(phosphonite), p-C(6)H(4)[N{P(OC(6)H(4)OMe-o)(2)}(2)](2) (P(2)N(Ph)NP(2)) () with [Rh(COD)Cl](2) in 1 : 2 and 1 : 1 molar ratio produce tetra- and polymetallic chelate complexes, [Rh(4)(COD)(2)(micro-Cl)(4)(P(2)N(Ph)NP(2))] () and [Rh(2)(micro-Cl)(2)(P(2)N(Ph)NP(2))](n) (), respectively. Similar reaction of with [Rh(COD)Cl](2) in dichloromethane-acetonitrile mixture furnishes a dinuclear complex, [Rh(2)Cl(2)(CH(3)CN)(2)(P(2)N(Ph)NP(2))] (). The reaction of or with CO affords a dinuclear carbonyl derivative, [Rh(2)Cl(2)(CO)(2)(P(2)N(Ph)NP(2))] (). Treatment of with 2 equivalents of pyrazine or 4,4'-bipyridine produce one-dimensional Rh(I) coordination polymers, [Rh(2)Cl(2)(C(4)H(4)N(2))(P(2)N(Ph)NP(2))](n) () and [Rh(2)Cl(2)(C(10)H(8)N(2))(P(2)N(Ph)NP(2))](n) in quantitative yields. The catalytic activity of Rh(I) complexes have been investigated in transfer hydrogenation reactions.

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