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Chen B, Ma S, Hurtado EJ, et al. A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules. Inorg Chem. 2007;46(21):8490-2doi: 10.1021/ic7014034.
Chen, B., Ma, S., Hurtado, E. J., Lobkovsky, E. B., & Zhou, H. C. (2007). A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules. Inorganic chemistry, 46(21), 8490-2. https://doi.org/10.1021/ic7014034
Chen, Banglin, et al. "A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules." Inorganic chemistry vol. 46,21 (2007): 8490-2. doi: https://doi.org/10.1021/ic7014034
Chen B, Ma S, Hurtado EJ, Lobkovsky EB, Zhou HC. A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules. Inorg Chem. 2007 Oct 15;46(21):8490-2. doi: 10.1021/ic7014034. Epub 2007 Sep 14. PMID: 17854181.
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Inorg Chem. 2007 Oct 15;46(21):8490-2. doi: 10.1021/ic7014034. Epub 2007 Sep 14.

A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules.

Inorganic chemistry

Banglin Chen, Shengqian Ma, Eric J Hurtado, Emil B Lobkovsky, Hong-Cai Zhou

Affiliations

  1. Department of Chemistry, University of Texas-Pan American, Edinburg, Texas 78541-2999, USA. [email protected]

PMID: 17854181 DOI: 10.1021/ic7014034

Abstract

A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).

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