Display options
Cite
Borchers C, Khomenko TI, Morozova OS, et al. Influence of graphite addition on the reactivity of Ti powder with H2 under ball milling. J Phys Chem B. 2006;110(1):196-204doi: 10.1021/jp054505t.
Borchers, C., Khomenko, T. I., Morozova, O. S., Galakhov, A. V., Kurmaev, E. Z., McNaughton, J., Yabloskikh, M. V., & Moewes, A. (2006). Influence of graphite addition on the reactivity of Ti powder with H2 under ball milling. The journal of physical chemistry. B, 110(1), 196-204. https://doi.org/10.1021/jp054505t
Borchers, C, et al. "Influence of graphite addition on the reactivity of Ti powder with H2 under ball milling." The journal of physical chemistry. B vol. 110,1 (2006): 196-204. doi: https://doi.org/10.1021/jp054505t
Borchers C, Khomenko TI, Morozova OS, Galakhov AV, Kurmaev EZ, McNaughton J, Yabloskikh MV, Moewes A. Influence of graphite addition on the reactivity of Ti powder with H2 under ball milling. J Phys Chem B. 2006 Jan 12;110(1):196-204. doi: 10.1021/jp054505t. PMID: 16471521.
Copy Download .nbib Format: NLM
Share it on

J Phys Chem B. 2006 Jan 12;110(1):196-204. doi: 10.1021/jp054505t.

Influence of graphite addition on the reactivity of Ti powder with H2 under ball milling.

The journal of physical chemistry. B

C Borchers, T I Khomenko, O S Morozova, A V Galakhov, E Z Kurmaev, J McNaughton, M V Yabloskikh, A Moewes

Affiliations

  1. Institute of Material Physics, University of Göttingen, Göttingen, Germany, Chemical Department, Lomonosov Moscow State University, Moscow, Russia.

PMID: 16471521 DOI: 10.1021/jp054505t

Abstract

The effect of graphite addition on the mechanism of hydrogen uptake by titanium during mechanochemical activation in hydrogen flow was studied using kinetic, structural, microscopic, and spectroscopic techniques. As was found, already a small graphite admixture of about 0.5 wt % changed the kinetics of mechanically induced H2 sorption and significantly stimulated Ti-H2 interaction. Two new types of occupation sites available for hydrogen were observed, which are characterized by low H2 desorption temperatures: about 650 and 750 K instead of 1000 K.

Publication Types