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Chem Commun (Camb). 2009 Apr 07;(13):1748-50. doi: 10.1039/b900367c. Epub 2009 Feb 12.

Functionalization of hexakis methanofullerene malonate crown-ethers: promising octahedral building blocks for molecular networks.

Chemical communications (Cambridge, England)

Philippe Pierrat, Sylvia Vanderheiden, Thierry Muller, Stefan Bräse

Affiliations

  1. Institut für organische Chemie, Universität Karlsruhe (TH), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.

PMID: 19294283 DOI: 10.1039/b900367c

Abstract

Hexaazido and hexaiodo macrocyclic methanofullerenes undergo high-yielding sixfold click reactions or sixfold Heck, Sonogashira and Suzuki cross-coupling reactions, respectively, to yield all organic building blocks for higher molecular architectures.

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