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Payne AD, Bojase G, Paddon-Row MN, et al. Practical synthesis of the dendralene family reveals alternation in behavior. Angew Chem Int Ed Engl. 2009;48(26):4836-9doi: 10.1002/anie.200901733.
Payne, A. D., Bojase, G., Paddon-Row, M. N., & Sherburn, M. S. (2009). Practical synthesis of the dendralene family reveals alternation in behavior. Angewandte Chemie (International ed. in English), 48(26), 4836-9. https://doi.org/10.1002/anie.200901733
Payne, Alan D, et al. "Practical synthesis of the dendralene family reveals alternation in behavior." Angewandte Chemie (International ed. in English) vol. 48,26 (2009): 4836-9. doi: https://doi.org/10.1002/anie.200901733
Payne AD, Bojase G, Paddon-Row MN, Sherburn MS. Practical synthesis of the dendralene family reveals alternation in behavior. Angew Chem Int Ed Engl. 2009;48(26):4836-9. doi: 10.1002/anie.200901733. PMID: 19455528.
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Angew Chem Int Ed Engl. 2009;48(26):4836-9. doi: 10.1002/anie.200901733.

Practical synthesis of the dendralene family reveals alternation in behavior.

Angewandte Chemie (International ed. in English)

Alan D Payne, Gomotsang Bojase, Michael N Paddon-Row, Michael S Sherburn

Affiliations

  1. Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia.

PMID: 19455528 DOI: 10.1002/anie.200901733

Abstract

Back from obscurity: The practical synthesis of the first six members of the fundamental class of acyclic branched oligoalkenes has been achieved. The syntheses allow access to the target compounds on multigram scales in good yields. Members of the family with even numbers of double bonds are significantly more stable than those with odd numbers (see picture), and exhibit different chemical reactivities in Diels-Alder reactions.

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