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Picot A, Dyer H, Buchard A, et al. Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones. Inorg Chem. 2010;49(4):1310-2doi: 10.1021/ic902339j.
Picot, A., Dyer, H., Buchard, A., Auffrant, A., Vendier, L., Le Floch, P., & Sabo-Etienne, S. (2010). Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones. Inorganic chemistry, 49(4), 1310-2. https://doi.org/10.1021/ic902339j
Picot, Alexandre, et al. "Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones." Inorganic chemistry vol. 49,4 (2010): 1310-2. doi: https://doi.org/10.1021/ic902339j
Picot A, Dyer H, Buchard A, Auffrant A, Vendier L, Le Floch P, Sabo-Etienne S. Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones. Inorg Chem. 2010 Feb 15;49(4):1310-2. doi: 10.1021/ic902339j. PMID: 20095639.
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Inorg Chem. 2010 Feb 15;49(4):1310-2. doi: 10.1021/ic902339j.

Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones.

Inorganic chemistry

Alexandre Picot, Hellen Dyer, Antoine Buchard, Audrey Auffrant, Laure Vendier, Pascal Le Floch, Sylviane Sabo-Etienne

Affiliations

  1. CNRS, LCC (Laboratoire de Chimie de Coordination), 205 Route de Narbonne, F-31077 Toulouse, France.

PMID: 20095639 DOI: 10.1021/ic902339j

Abstract

This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H(2))(H(2)NNPP)(PCy(3))][BArf(4)] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.

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