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Chem Commun (Camb). 2010 Jan 07;46(1):85-7. doi: 10.1039/b920090h. Epub 2009 Nov 19.

Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.

Chemical communications (Cambridge, England)

Pei-Jen Tiong, A Daniel Schofield, Jonathan D Selby, Ainara Nova, Eric Clot, Philip Mountford

Affiliations

  1. Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK.

PMID: 20024301 DOI: 10.1039/b920090h

Abstract

Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

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