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Dalton Trans. 2010 Jun 28;39(24):5614-6. doi: 10.1039/c003135f. Epub 2010 May 19.

Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes.

Dalton transactions (Cambridge, England : 2003)

Benjamin D Roach, Ross S Forgan, Peter A Tasker, Ronald M Swart, John Campbell, Fiona E McAllister, Andrew P Stopford, Bridgette J Duncombe

Affiliations

  1. School of Chemistry, University of Edinburgh, King's Buildings, Edinburgh, UK EH9 3JJ.

PMID: 20485809 DOI: 10.1039/c003135f

Abstract

Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

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