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Chem Commun (Camb). 2010 Jun 28;46(24):4387-9. doi: 10.1039/c002725a. Epub 2010 May 12.

Ascorbate mediated copper catalyzed reductive cross-coupling of disulfides with aryl iodides.

Chemical communications (Cambridge, England)

Marek Martinek, Michal Korf, Jiri Srogl

Affiliations

  1. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Praha 6, Czech Republic.

PMID: 20461276 DOI: 10.1039/c002725a

Abstract

The concept of using ascorbic acid as a mediator/ reducing agent in a Cu(I) catalyzed process is introduced and further demonstrated on a cross-coupling reaction of aryl iodides with disulfides.

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