Display options
Cite
Jin Z, Zhang XB, Xie DX, et al. Clicking fluoroionophores onto mesoporous silicas: a universal strategy toward efficient fluorescent surface sensors for metal ions. Anal Chem. 2010;82(15):6343-6doi: 10.1021/ac101305e.
Jin, Z., Zhang, X. B., Xie, D. X., Gong, Y. J., Zhang, J., Chen, X., Shen, G. L., & Yu, R. Q. (2010). Clicking fluoroionophores onto mesoporous silicas: a universal strategy toward efficient fluorescent surface sensors for metal ions. Analytical chemistry, 82(15), 6343-6. https://doi.org/10.1021/ac101305e
Jin, Zhen, et al. "Clicking fluoroionophores onto mesoporous silicas: a universal strategy toward efficient fluorescent surface sensors for metal ions." Analytical chemistry vol. 82,15 (2010): 6343-6. doi: https://doi.org/10.1021/ac101305e
Jin Z, Zhang XB, Xie DX, Gong YJ, Zhang J, Chen X, Shen GL, Yu RQ. Clicking fluoroionophores onto mesoporous silicas: a universal strategy toward efficient fluorescent surface sensors for metal ions. Anal Chem. 2010 Aug 01;82(15):6343-6. doi: 10.1021/ac101305e. PMID: 20590097.
Copy Download .nbib Format: NLM
Share it on

Anal Chem. 2010 Aug 01;82(15):6343-6. doi: 10.1021/ac101305e.

Clicking fluoroionophores onto mesoporous silicas: a universal strategy toward efficient fluorescent surface sensors for metal ions.

Analytical chemistry

Zhen Jin, Xiao-Bing Zhang, De-Xun Xie, Yi-Jun Gong, Jing Zhang, Xin Chen, Guo-Li Shen, Ru-Qin Yu

PMID: 20590097 DOI: 10.1021/ac101305e

Abstract

Mesoporous SBA-15 silica is an excellent support for constructing fluorescent surface sensors. In this letter, we reported a two-step surface reaction involved strategy to construct efficient fluorescent surface sensors for metal ions by clicking fluoroionophores onto azide-functionalized SBA-15. Our experimental results indicate that such a strategy exhibits an obviously higher loading efficiency within commercial SBA-15 than a previously reported strategy. As a proof-of-concept, a newly designed alkyne-functionalized Hg(2+) fluoroionophore was grafted onto SBA-15 to form a fluorescent Hg(2+) surface sensor. It shows improved sensitivity and selectivity than the fluoroionophore itself working in the solution phase with a detection limit of 2.0 x 10(-8) M for Hg(2+).

Publication Types