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Nano Lett. 2010 Jul 14;10(7):2562-7. doi: 10.1021/nl101198b.

Hierarchical TiO2 photoanode for dye-sensitized solar cells.

Nano letters

F Sauvage, F Di Fonzo, A Li Bassi, C S Casari, V Russo, G Divitini, C Ducati, C E Bottani, P Comte, M Graetzel

Affiliations

  1. Institut des Sciences et Ingenieurie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne, Switzerland.

PMID: 20565087 DOI: 10.1021/nl101198b

Abstract

Hierarchical or one-dimensional architectures are among the most exciting developments in material science these recent years. We present a nanostructured TiO(2) assembly combining these two concepts and resembling a forest composed of individual, high aspect-ratio, treelike nanostructures. We propose to use these structures for the photoanode in dye-sensitized solar cells, and we achieved 4.9% conversion efficiency in combination with C101 dye. We demonstrate this morphology beneficial to hamper the electron recombination and also mass transport control in the mesopores when solvent-free ionic liquid electrolyte is used.

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