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Chem Commun (Camb). 2010 Sep 21;46(35):6566-8. doi: 10.1039/c0cc01746a. Epub 2010 Aug 16.

Selective polymerization of polypyrrole in silica mesopores using an in situ generated oxidizing agent on a silica surface.

Chemical communications (Cambridge, England)

Yongju Jung, Ryan L Spray, Jin Hoe Kim, Ji Man Kim, Kyoung-Shin Choi

Affiliations

  1. Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA.

PMID: 20714553 DOI: 10.1039/c0cc01746a

Abstract

A novel method that selectively polymerizes pyrrole on the silica surface without inducing polymerization in bulk solution is developed, which is based on in situ generation of the NO(+) ion as an oxidant at the silica surface.

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