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J Am Chem Soc. 2010 Nov 10;132(44):15542-3. doi: 10.1021/ja1082969.

Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy.

Journal of the American Chemical Society

Smitha Surendran Thamarath, Joachim Heberle, P J Hore, Tilman Kottke, Jörg Matysik

Affiliations

  1. Leiden Institute of Chemistry, Einsteinweg 55, 2300 RA Leiden, The Netherlands.

PMID: 20958069 DOI: 10.1021/ja1082969

Abstract

Until now, the solid-state photo-CIDNP effect, discovered in 1994 by Zysmilich and McDermott, has been observed selectively in photosynthetic systems. Here we present the first observation of this effect in a nonphotosynthetic system, the blue-light photoreceptor phototropin LOV1-C57S using (13)C magic-angle spinning (MAS) NMR.

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