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Alsobrook AN, Hauser BG, Hupp JT, et al. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials. Chem Commun (Camb). 2010;46(48):9167-9doi: 10.1039/c0cc03507f.
Alsobrook, A. N., Hauser, B. G., Hupp, J. T., Alekseev, E. V., Depmeier, W., & Albrecht-Schmitt, T. E. (2010). Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials. Chemical communications (Cambridge, England), 46(48), 9167-9. https://doi.org/10.1039/c0cc03507f
Alsobrook, Andrea N, et al. "Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials." Chemical communications (Cambridge, England) vol. 46,48 (2010): 9167-9. doi: https://doi.org/10.1039/c0cc03507f
Alsobrook AN, Hauser BG, Hupp JT, Alekseev EV, Depmeier W, Albrecht-Schmitt TE. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials. Chem Commun (Camb). 2010 Dec 28;46(48):9167-9. doi: 10.1039/c0cc03507f. Epub 2010 Nov 01. PMID: 21042646.
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Chem Commun (Camb). 2010 Dec 28;46(48):9167-9. doi: 10.1039/c0cc03507f. Epub 2010 Nov 01.

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials.

Chemical communications (Cambridge, England)

Andrea N Alsobrook, Brad G Hauser, Joseph T Hupp, Evgeny V Alekseev, Wulf Depmeier, Thomas E Albrecht-Schmitt

Affiliations

  1. Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.

PMID: 21042646 DOI: 10.1039/c0cc03507f

Abstract

Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M(2)[(UO(2))(6)(PO(3)CH(2)CO(2))(3)O(3)(OH)(H(2)O)(2)]·16H(2)O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 Å in diameter that are filled with co-crystallized water molecules. [Cd(3)(UO(2))(6)(PO(3)CH(2)CO(2))(6)(H(2)O)(13)]·6H(2)O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO(2) uptake of 40 m(2) g(-1) at 273 K, and no uptake of N(2) at 77 K.

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